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The formula unit of the title mol­ecular complex, 2C 16 H 16 N 2 O 3 ·C 16 H 16 N 2 O 2 , consists of two ( E )- N ′-[1-(2-hy­droxy­phen­yl)ethyl­idene]-2-phen­oxy­acetohydrazide mol­ecules and one mol­ecule of 2,2′-(1,1′-azinodiethyl­idyne)diphenol, with the latter located on a crystallographic inversion center. The acetohydrazide mol­ecules are linked into a supermolecular chain along the  c  axis by inter­molecular N—H⋯O hydrogen bonds. There are also intra­molecular O—H⋯N hydrogen bonds in both the acetohydrazide and diphenol mol­ecules.

(E)-N′-[1-(2-Hydroxyphenyl)ethylidene]-2-phenoxyacetohydrazide–2,2′-(1,1′-azinodiethylidyne)diphenol (2/1)