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In the title compound, [Bi(C 20 H 17 N)(ClO 4 )] or C 20 H 17 BiClNO 4 , the Bi III  ion assumes a distorted ψ trigonal–bipyramidal geometry, with two C atoms and the electron lone pair of the Bi atom at the equatorial positions and an amine N atom and a perchlorate O atom at the apical positions. Weak inter­molecular C—H⋯O hydrogen bonding is present in the crystal structure.

6-Phenyl-6,7-dihydrodibenzo[c,f][1,5]azabismocin-12(5H)-yl perchlorate