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The title compound, {(C 14 H 18 N 2 )[Pb 2 I 6 ]}  n  , consists of discrete 1,1′-dimethyl-4,4′-(ethane-1,2-di­yl)dipyridinium cations and one-dimensional [Pb 2 I 6 ]  n   anions. The organic cation has an inversion center at the mid-point of the ethane C—C bond. In the anion, the Pb II  atom is coordinated by six I atoms in a distorted octa­hedral geometry. The I atoms bridge the Pb II  atoms into a polymeric chain running along [001]. These inorganic chains are separated by the isolated organic cations.

catena-Poly[1,1′-dimethyl-4,4′-(ethane-1,2-diyl)dipyridinium [lead(II)-tri-μ-iodido-lead(II)-tri-μ-iodido]]