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In the title compound, [Cu(C 9 H 6 N 3 O 2 ) 2 (H 2 O) 4 ]·2H 2 O, the Cu II  atom lies on an inversion center and is six-coordinated by two N atoms from two 4-(1,2,4-triazol-4-yl)benzoate ligands and four water mol­ecules in a distorted octa­hedral geometry. In the crystal, inter­molecular O—H⋯O hydrogen bonds lead to a three-dimensional supra­molecular network. Intra­molecular O—H⋯N hydrogen bonds and π–π inter­actions between the benzene rings and between the benzene and triazole rings [centroid–centroid distances = 3.657 (1) and 3.752 (1) Å] are observed.

Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN1]copper(II) dihydrate

Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN¹]copper(II) dihydrate