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In the title organic–inorganic hybrid compound, (C 4 H 10 NO) 3 [H 6 CrMo 6 O 24 ]·4H 2 O, the Anderson-type [H 6 CrMo 6 O 24 ] 3−  polyoxoanion is centrosymmetric, with the Cr III  ion lying on an inversion center. One of the two crystallographiclly independent morpholinium cations is half-occupied. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds link the cations, polyoxoanions and uncoordinated water mol­ecules.

Tris(morpholinium) hexa-μ3-hydroxido-hexa-μ2-oxido-dodecaoxidohexamolybdenum(VI)chromate(III) tetrahydrate

Tris(morpholinium) hexa-μ₃-hydroxido-hexa-μ₂-oxido-dodecaoxidohexamolybdenum(VI)chromate(III) tetrahydrate