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The acetonitrile ligand in the title compound, [W(CH 3 CN)(CO) 5 ], is coordinated end-on to a penta­carbonyl­tungsten(0) fragment with a W—N bond length of 2.186 (4) Å, completing an octa­hedral coordination environment around the W atom.

(Acetonitrile-κN)pentacarbonyltungsten(0)