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In the title coordination polymer, {[Ho(C 7 H 2 NO 5 )(H 2 O) 3 ]·H 2 O}  n  , the Ho III  atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxyl­ate trianion, two monodentate anions and three water mol­ecules, forming a distorted bicapped trigonal–prismatic HoNO 7  coordination geometry. The anions bridge adjacent Ho III  ions into double chains. Adjacent chains are further connected into sheets. O—H⋯O hydrogen bonds involving both coordinated and uncoordinated water mol­ecules generate a three-dimensional supra­molecular framework.

Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)holmium(III)] monohydrate]

Poly[[triaqua(μ₃-4-oxidopyridine-2,6-dicarboxylato)holmium(III)] monohydrate]