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In the title compound, [KGd(C 10 H 2 O 8 )(H 2 O) 2 ]  n  , the Gd 3+  ion is nine-coordinated by eight O atoms from five individual benzene-1,2,4,5-tetra­carboxyl­ate (btec) ligands and one water mol­ecule, and the K +  ion is eight-coordinated by six O atoms from five individual btec ligands and two water mol­ecules. In the crystal, the btec half-mol­ecules are completed by crystallographic inversion symmetry. GdO 9  and KO 8  polyhedra are connected, forming layers in the  ab  plane, which are further inter­connected by μ 8 - or μ 12 -bridging btec ligands, forming a three-dimensional structure.

Poly[μ-aqua-aqua(μ-benzene-1,2,4,5-tetracarboxylato)gadolinate(III)potassium(I)]