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In the title mol­ecule, [Sb 2 (C 6 H 5 ) 6 (C 4 H 4 Br 2 O 4 )(CH 3 O) 2 ], two [Sb(CH 3 O)Ph 3 ] +  units are linked by the two carboxyl­ate O atoms of a  meso -2,3-dibromo­succinate bridging ligand, forming a dinuclear compound. The Sb IV  atom is five-coordinated in a slightly distorted trigonal–bipyramid geometry by phenyl C atoms in the equatorial positions and two O atoms in the axial positions. C—H⋯O inter­actions link the mol­ecules into a two-dimensional network parallel to (010). The —CH— group of the centrosymmetric 2,3-dibromosuccinate anion is disordered over two sites in a 0.6:0.4 ratio.

(μ-2,3-Dibromosuccinato-κ2O1:O4)bis[methanolato-κO)triphenylantimony(V)]

(μ-2,3-Dibromosuccinato-κ²O¹:O⁴)bis[methanolato-κO)triphenylantimony(V)]