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In the crystal structure of the title compound, [FeCl 2 (C 10 H 8 N 2 ) 2 ]ClO 4 , the coordination around the Fe III  atom is approximately octa­hedral. The equatorial positions are occupied by two N atoms from two 2,2′-bipyridyl ligands [Fe—N = 2.121 (5) and 2.147 (5) Å] and two Cl atoms [Fe—Cl = 2.220 (2) and 2.2074 (18) Å]. Weak inter­molecular C—H⋯O and C—H⋯Cl hydrogen bonds and C—H⋯π inter­actions consolidate the crystal packing.

cis-Bis(2,2′-bipyridine-κ2N,N′)dichloridoiron(III) perchlorate

cis-Bis(2,2′-bipyridine-κ²N,N′)dichloridoiron(III) perchlorate