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In the title complex, [PdI 2 (C 24 H 31 N 3 ) 2 ]·2C 6 H 6 , the Pd 2+  ion is located on an inversion centre in a slightly distorted square-planar geometry. The angle between the I 2 C 2  square plane and the mean plane of the  N -heterocyclic carbene ring is 79.8 (2)°, with I—Pd—C—N torsion angles of −81.1 (6) and −78.2 (5)°. The Pd—carbene and Pd—I distances are 2.016 (6) and 2.5971 (10) Å, respectively.

trans-Bis{1-[2-(2,6-diisopropylanilino)phenyl]-3-isopropylimidazolin-2-ylidenyl-κC2}diiodidopalladium(II) benzene disolvate

trans-Bis{1-[2-(2,6-diisopropylanilino)phenyl]-3-isopropylimidazolin-2-ylidenyl-κC²}diiodidopalladium(II) benzene disolvate