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The V IV  atom in the title complex, [V(C 11 H 13 BrClN 2 O)(C 5 H 7 O 2 )O], is six-coordinated by one phenolate O, one imino N and one amino N atom of the tridentate anionic Schiff base ligand, by one oxide O atom, and by two O atoms of an acetyl­acetonate anion, forming a distorted  cis -VN 2 O 4  octa­hedral coordination geometry. The deviation of the V atom from the plane defined by the three donor atoms of the Schiff base ligand and one O atom of the acetyl­acetone ligand towards the oxide O atom is 0.256 (2) Å.

acta crystallographica. section e

(Acetylacetonato-κ2O,O′)(2-bromo-4-chloro-6-{[2-(dimethylamino)ethylimino]methyl}phenolato-κ3N,N′,O)oxidovanadium(IV)