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Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η 5 -C 9 H 7 )Cl(PPh 3 ) 2 ] is treated with 1,4-bis­(diphenyl­phosphan­yl)butane in refluxing toluene yielding the title compound, [Ru(C 9 H 7 )Cl(C 28 H 28 P 2 )]. The Ru II  atom has a typical piano-stool coordination, defined by the indenyl ligand, one Cl atom and two phosphanyl P atoms. The Ru—P bond lengths are 2.2502 (9) and 2.2968 (8) Å.

[1,4-Bis(diphenylphosphanyl)butane-κ2P,P′]chlorido(η5-indenyl)ruthenium(II)

[1,4-Bis(diphenylphosphanyl)butane-κ²P,P′]chlorido(η⁵-indenyl)ruthenium(II)