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The title compound, [Fe(C 7 H 5 FN)Cl(C 3 H 9 P) 3 ], was obtained as a product of the reaction of [Fe(Me 3 P) 4 ] with a molar equivalent of (2-chloro-6-fluoro­phen­yl)methanimine in diethyl ether. This compound is sensitive to air, and rapidly decomposes when exposed to air for a few minutes. The Fe atom has an octa­hedral coordination geometry in which the bidentate fluoro­phenyl methanimine ligand forms the equatorial plane with the Cl atom and one of the trimethyl­phosphane ligands. The other two trimethyl­phosphane ligands are located in the axial positions. In the crystal, an N—H⋯Cl hydrogen bond occurs.

Chlorido(2-iminomethyl-3-fluorophenyl-κ2C1,N)tris(trimethylphosphane-κP)iron

Chlorido(2-iminomethyl-3-fluorophenyl-κ²C¹,N)tris(trimethylphosphane-κP)iron