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In the mixed-valence Cu I /Cu II  coordination polymer, [Cu 2 Cl 3 (C 20 H 14 N 4 )]  n  , the two Cu atoms are bridged to a pair of Cl atoms across a centre of inversion. The monovalent metal atoms is coordinated by a pyridine N atom as well as by three Cl atoms in a tetra­hedral CuNCl 3  geometry. The divalent metal atom is  N , N ′, N ′′-chelated by the heterocycle, and it exists in a square-pyramidal CuN 3 Cl 2  geometry; the apical site is occupied by the second bridging Cl atom. The bridging modes of the Cl atoms and the heterocycle give rise to the formation of a layered arrangement parallel to (001).

Poly[μ2-chlorido-dichlorido[μ2-4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine]copper(I)copper(II)]

Poly[μ₂-chlorido-dichlorido[μ₂-4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine]copper(I)copper(II)]