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The mol-ecular structure of the title compound, C(18)H(23)N(3)S, shows it to be a derivative of an amino-thio-phenol possessing a tetra-methyl-guanidine group with a localized C=N double bond of 1.304 (2) Å and a protected thiol functional group as an S-benzyl thio-ether. The two aromatic ring planes make a dihedral angle of 67.69 (6)°.

2-[2-(Benzylsulfanyl)phenyl]-1,1,3,3-tetramethylguanidine