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In the title compound, [Zn(C 12 H 9 O 2 ) 2 (C 12 H 12 N 2 )]·0.5H 2 O, the water mol­ecule lies on a twofold rotation axis. The Zn II  atom is coordinated by three O atoms from two 1-naphthyl­acetate ligands, one monodentate and the other asymmetric bidentate chelate, and two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand, giving an irregular environment. In the crystal, the complex mol­ecules are inter­linked through the water mol­ecule by O—H⋯O carboxyl­ate  hydrogen bonds, together with weak C—H⋯O and bipyridine ring π–π stacking inter­actions [ring centroid separation = 3.761 (2) Å], giving a two-dimensional network structure.

acta crystallographica. section e

(5,5′-Dimethyl-2,2′-bipyridine-κ2N,N′)(1-naphthylacetato-κO)(1-naphthylacetato-κ2O,O′)zinc hemihydrate