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In the title complex, [CoK 2 (C 3 H 2 O 4 ) 2 (H 2 O) 4 ]  n  , the Co atom is located on a position with site symmetry 2/ m , the K atom and one water mol­ecule are located on a mirror plane, and the malonate and one water mol­ecule are located on a twofold rotation axis. The K I  atom is seven-coordinated by four carboxyl­ate O atoms from four malonate ligands and by three water O atoms, forming a distorted polyhedron. The Co II  atom is in an almost octa­hedral environment formed by four carboxyl­ate O atoms from two malonate ligands and two water O atoms. The structure consists of layers parallel to (20    ) built up from edge-sharing KO 7  and CoO 6  polyhedra, which are connected by O—H⋯O hydrogen bonding including water mol­ecules into a three-dimensional network.

Poly[di-μ-aqua-diaqua-di-μ6-malonato-cobalt(II)dipotassium(I)]

Poly[di-μ-aqua-diaqua-di-μ₆-malonato-cobalt(II)dipotassium(I)]