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The chemically achiral title mol-ecule, [Ti(C(4)H(10)N)(2)(C(21)H(16)N(2))], crystallizes in the chiral space group P2(1). All three N atoms coordinating to the Ti(IV) atom adopt planar environments [sums of valence angles = 359.5 (6), 360.0 (7) and 360.0 (6)°], which is indicative of pπ-dπ donation from all of these N atoms to the metal and, thus, of the formal 18 e(-) nature of the complex. The overall coordination about the Ti(IV) atom is distorted tetra-hedral, assuming the cyclo-penta-dienyl ring occupies one coordination site. The Ti-N(imidazole) amide-type bond is longer by approximately 0.16 Å than the other two Ti-N(amide) bonds.

{2-[(η5-Cyclopentadienyl)diphenylmethyl]-1H-imidazolido-κN}bis(N,N-diethylamido)titanium(IV)

{2-[(η⁵-Cyclopentadienyl)diphenylmethyl]-1H-imidazolido-κN}bis(N,N-diethylamido)titanium(IV)