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The centrosymmetric binuclear Cu II  title complex, [Cu 2 (C 8 H 7 O 3 ) 4 (CH 3 CN) 2 ], has a paddle-wheel-type structure [Cu—Cu distance = 2.6433 (3) Å]. Each Cu II  ion is coordin­ated by four O atoms from two 3-meth­oxy­benzoate ligands and one acetonitrile N atom in a square-pyramidal geometry.

Tetrakis(μ-3-methoxybenzoato-κ2O1:O1′)bis[acetonitrilecopper(II)]

Tetrakis(μ-3-methoxybenzoato-κ²O¹:O^1′)bis[acetonitrilecopper(II)]