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In the title compound, [Fe(C 38 H 38 N 10 )](ClO 4 ) 2 ·CH 3 OH, the Fe II  atom has a distorted octa­hedral coordination environment with four benzimidazol N atoms and two amino N atoms from an  N , N , N ′, N ′-tetra­kis­(benzimidazol-2-ylmeth­yl)cyclo­hexane-1,2- trans -diamine ligand. The uncoordinated solvent methanol mol­ecule is hydrogen bonded to an O atom of a perchlorate anion. One of the perchlorate anions is disordered over two sets of sites with occupancy factors of 0.539 (14) and 0.461 (14). N—H⋯O and C—H⋯O hydrogen bonds, as well as π–π stacking inter­actions between the imidazol rings and between the imidazol and benzene rings [centroid–centroid distances = 3.714 (2) and 3.705 (2) Å] give rise to a three-dimensional network.

acta crystallographica. section e

[N,N,N′,N′-Tetrakis(benzimidazol-2-ylmethyl)cyclohexane-1,2-trans-diamine]iron(II) bis(perchlorate) methanol solvate