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In the title compound, [Li 2 (CF 3 SO 2 NSO 2 CF 3 ) 2 (CH 3 CN) 2 ]  n  , two Li +  cations reside on crystallographic inversion centers, each coordinated by six O atoms from bis(trifluoromethanesulfonyl)imide (TFSI − ) anions. The third Li +  cation on a general position is four-coordinated by two anion O atoms and two N atoms from acetonitrile mol­ecules in a tetra­hedral geometry.

Poly[bis(acetonitrile-κN)bis[μ3-bis(trifluoromethanesulfonyl)imido-κ4O,O′:O′′:O′′′]dilithium]

Poly[bis(acetonitrile-κN)bis[μ₃-bis(trifluoromethanesulfonyl)imido-κ⁴O,O′:O′′:O′′′]dilithium]