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In the title compound, [Co(C 14 H 16 N 2 O 4 ) 2 (H 2 O) 2 ]  n  , the Co II  atom, lying on an inversion center, is coordinated by six O atoms in a distorted octa­hedral geometry. The Co II  atoms are bridged by the nitronyl nitroxide ligands into a tape-like structure along the  b  axis. The tapes are further connected by O—H⋯O hydrogen bonds, forming a layer parallel to the  bc  plane.

catena-Poly[[diaquacobalt(II)]bis[μ-2-(4-carboxylatophenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl 3-oxide]]