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The asymmetric unit of the title compound, [Cd(NCS) 2 (C 5 H 5 N) 2 ]  n  , consists of two crystallographically independent Cd II  cations, four thio­cyanato anions and four pyridine ligands. The Cd II  atoms are each coordinated by four N atoms from two pyridine ligands and two thio­cyanato anions, each in a mutually  cis  orientation, and by two S atoms from two adjacent thio­cyanato anions within a slightly distorted octa­hedral coordination environment. The Cd II  atoms are μ-1,3-bridged  via  the thio­cyanato anions into polymeric chains parallel to [001]. The Cd II ⋯Cd II  intra­chain separations range between 5.9688 (6) and 6.0195 (6) Å, whereas the shortest Cd II ⋯Cd II  inter­chain separations are 7.8272 (7) and 8.6312 (6) Å.

catena-Poly[[bis(pyridine-κN)cadmium]-di-μ2-thiocyanato-κ2N:S;κ2S:N]

catena-Poly[[bis(pyridine-κN)cadmium]-di-μ₂-thiocyanato-κ²N:S;κ²S:N]