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The title compound, [Ni(C 15 H 24 NSi) 2 ], is a homoleptic metal–η 3 -aza­allyl centrosymmetric complex containing two aza­allyl ligands bound in an η 3 -manner to an Ni II  atom located on a center of symmetry. The overall coordination about the Ni II  atom is square-planar. The C and N atoms of the aza­allyl group are  sp2 -hybridized. The uneven Ni—C and Ni—N distances [2.045 (5)/2.060 (6) and 1.916 (5) Å] are influenced by a steric hindering effect from the nearby benzene ring.

Bis(η3-2-tert-butyl-1-trimethylsilyl-3-phenyl-1-azaallyl)nickel(II)

Bis(η³-2-tert-butyl-1-trimethylsilyl-3-phenyl-1-azaallyl)nickel(II)