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In the title compound, [Ag 2 (C 14 H 14 N 4 ) 2 ](C 14 H 8 N 2 O 4 )·2H 2 O, each of the two unique Ag +  ions is two-coordinated by two N atoms from two different 1,4-bis­[(imidazol-1-yl)meth­yl]benzene ligands in an almost linear fashion [N—Ag—N = 170.34 (10) and 160.25 (10)°]. The 4,4′-diazenediyldibenzoate anions do not coordinate to Ag. O—H⋯O hydrogen bonds stabilize the crystal structure.

acta crystallographica. section e

Poly[[[silver(I)-μ-1,4-bis[(imidazol-1-yl)methyl]benzene-κ2N3:N3′-silver(I)-μ-1,4-bis[(imidazol-1-yl)methyl]benzene-κ2N3:N3′] 4,4′-diazenediyldibenzoate] dihydrate]