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In the centrosymmetric dinuclear title complex, [Cu 2 (C 5 H 6 O 4 ) 2 (C 12 H 18 N 2 ) 2 (H 2 O) 2 ], the Cu II  atom displays a dis­torted square-pyramidal coordination environment with the basal plane occupied by two phenanthroline N atoms and two O atoms from different glutarate dianions while a water mol­ecule is located at the apical position. Of the two water H atoms, one is engaged in an intra­molecular hydrogen bond with a free oxygen of the dianion whereas the second is engaged in an inter­molecular hydrogen bond, building a corrugated layer parallel to (100). These layers are further connected through π–π stacking inter­actions involving symmetry-related phenanthroline rings [centroid–centroid distance = 3.5599 (17) and 3.5617 (18) Å], building a three dimensionnal network. C—H⋯π inter­actions involving the phenanthroline ring system are also observed.

Di-μ-glutarato-κ4O1:O5-bis[aqua(1,10-phenanthroline-κ2N,N′)copper(II)]

Di-μ-glutarato-κ⁴O¹:O⁵-bis[aqua(1,10-phenanthroline-κ²N,N′)copper(II)]