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The title compound, [Zr 3 (C 14 H 20 Si 2 ) 3 O 3 ], consists of three disila-bridged zirconocene units, which are connected  via  an oxide ligand, forming a nearly planar six-membered ring with a maximum displacement of 0.0191 (8) Å. The compound was isolated as a by-product from a mixture of [(C 5 H 4 SiMe 2 ) 2 ZrCl 2 ] and Li[AlH 4 ] in Et 2 O.

acta crystallographica. section e

cyclo-Tri-μ-oxido-tris{[(η5,η5)-1,2-bis(cyclopentadienyl)-1,1,2,2-tetramethyldisilane]zirconium(IV)}: a trimeric disila-bridged oxidozirconocene