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In the title compound, C 16 H 12 F 4 N 2 O 3 S, the pyrimidine ring adopts a half-chair conformation; the mean plane formed by the ring atoms excluding the C atom bonded to the thio­phen-2-ylcarbonyl group has an r.m.s. deviation of 0.059 Å. The dihedral angle between the benzene and thio­phene rings is 62.26 (7)°. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯O hydrogen bond, generating an  S (6) ring. In the crystal, adjacent mol­ecules are connected  via  a centrosymmetric  R22 (6) motif, formed by N—H⋯O hydrogen bonds.

4-(3-Fluorophenyl)-6-hydroxy-5-(thiophen-2-ylcarbonyl)-6-trifluoromethyl-1,3-diazinan-2-one