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In the title compound, {[Zn(C 8 H 5 N 2 O 2 S) 2 ]·3H 2 O}  n  , the Zn II  atom, lying on a twofold rotation axis, is four-coordinated by two S atoms and two O atoms from four 2-sulfido-1 H -benzimidazol-3-ium-5-carboxyl­ate (H 2 mbidc) ligands in a distorted tetra­hedral geometry. Two H 2 mbidc ligands bridge two Zn II  atoms, generating a double-chain along [    01]. Adjacent chains are linked by N—H⋯O and O—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network. One of the two water molecules also lies  on a twofold rotation axis.

acta crystallographica. section e

catena-Poly[[zinc-bis(μ-2-sulfido-1H-benzimidazol-3-ium-5-carboxylato)-κ2O:S;κ2S:O] trihydrate]