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In the title complex, [Zn(NCO) 2 (C 7 H 8 N 4 ) 2 ], the Zn II  ion exhibits a distorted tetra­hedral coordination geometry. The coordination environment is formed by two 5,7-dimethyl-1,2,4-triazolo[1,5- a ]pyrimidine (dmtp) ligands, coordinated through the N atom in position 3, and two cyanate anions inter­acting by their N atoms. Supra­molecular dimers are generated by stacking inter­actions between the pyrimidine rings of two ligands related by an inversion center [centroid–centroid distance = 3.5444 (18) Å].

Bis(cyanato-κN)bis(5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine-κN3)zinc

Bis(cyanato-κN)bis(5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine-κN³)zinc