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In the title adduct, C 6 H 4 Cl 3 N·C 6 H 3 N 3 O 7 , the two benzene rings are almost coplanar, with a dihedral angle of 1.19 (1)° and an inter-ring centroid–centroid separation of 4.816 (2) Å. The crystal structure is stabilized by inter­molecular N—H⋯O nitro  hydrogen bonds, giving a chain structure. In addition, there are phenol–nitro O—H⋯O inter­actions.

Picric acid–2,4,6-trichloroaniline (1/1)