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The asymmetric unit of the title compound, [Cd 2 (C 8 H 10 O 4 ) 2 (C 23 H 14 N 4 O) 2 (H 2 O) 2 ]·H 2 O, consists of one half of the dimeric complex, which lies about an inversion centre, and a half-occupancy solvent water mol­ecule on a general position. Each Cd II  cation is six-coordinated by the two N atoms from one 1-(1 H -imidazo[4,5- f ][1,10]phenanthrolin-2-yl)naphthalen-2-ol ( L ) ligand and three O atoms from two different 1,4-chdc 2−  ligands (1,4-H 2 chdc = cyclo­hexane-1,4-dicarb­oxy­lic acid), two coordinating in a bidentate fashion and the other in a monodentate fashion. The distorted octa­hedral coordination sphere is completed by a coordinated water mol­ecule. The Cd II  atoms are each bridged by two 1,4-chdc 2−  ligands, forming an inversion dimer with the  L  ligands located on the outside of the dimeric unit. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, O—H⋯O and N—H⋯O hydrogen-bonding inter­actions stabilize the packing.

Bis(μ-cyclohexane-1,4-dicarboxylato)bis{aqua[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate