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The title compound, [Fe(NO) 2 (C 18 H 12 F 3 P) 2 ]·CHCl 3 , belongs to the family of metal dinitrosyl compounds with the general formula Fe(NO) 2 ( L )  x  , referred to collectively as ‘dinitrosyl iron compounds’ (DNICs). Herein we report the structure of a dinitrosyl iron diphosphane complex, (Fe(NO) 2L2 , with  L  = P(C 6 H 4 - p -F) 3 . The structure includes one metal complex mol­ecule and one chloro­form solvent mol­ecule. The iron atom is tetra­hedrally coordinated with two phosphane ligands and with two NO groups with Fe—N—O angles of 178.1 (2) and 177.0 (2)°.

Dinitrosylbis[tris(4-fluorophenyl)phosphane]iron chloroform monosolvate