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The enanti­opure title compound, C 4 H 10 NO 2+ ·Cl − ·H 2 O, forms a two-dimensional network by inter­molecular hydrogen bonding parallel to (010). Non-merohedral twinning with a twofold rotation about the reciprocal  c * axis as twin operation was taken into account during intensity integration and structure refinement. This twinning leads to alternative orientations of the stacked hydrogen-bonded layers.

L-Alanine methyl ester hydrochloride monohydrate