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In the title compound, [Ni(NCS) 2 (CH 3 CN) 2 ]  n  , the Ni II  cation is coordinated by two  N -bonded and two  S -bonded thio­cyanate anions, as well as two acetonitrile mol­ecules in an octa­hedral NiN 4 S 2  coordination mode. The asymmetric unit comprises one nickel cation, two thio­cyanate anions and two actonitrile mol­ecules. In the crystal, the Ni II  cations are connected by bridging thio­cyanate anions into a three-dimensional coordination network.

Poly[bis(acetonitrile-κN)di-μ-thiocyanato-κ2N,S;κ2S,N-nickel(II)]

Poly[bis(acetonitrile-κN)di-μ-thiocyanato-κ²N,S;κ²S,N-nickel(II)]