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Iodine adds across both triple bonds of 4,4′-bis­(prop-2-yn­­yl­oxy)biphenyl, yielding the 4,4′-bis­(2,3-diiodo­all­yloxy)biphenyl title compound, C 18 H 14 I 4 O 2 ; the 2,3-diiodo­ally­oxy substituents have the I atoms in an  E  configuration. In the biphenyl portion of the mol­ecule, the aromatic rings are inclined by 37.8 (2)°.

4,4′-Bis[(E)-(2,3-diiodoprop-2-en-1-yl)oxy]biphenyl