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In the title coordination polymer, [Ce 2 (C 10 H 8 O 4 ) 3 (H 2 O) 2 ]  n  , each Ce III  atom is nine-coordinated by eight O atoms from six different 1,3-phenyl­enediacetate (pda) bivalent anions and one O atom from a coordinated water mol­ecule, forming a distorted tricapped trigonal–prismatic coordination geometry. Eight Ce III  ions and twelve pda ligands form a large [Ce 8 (pda) 12 ] ring, and four Ce III  ions and six pda ligands form a small [Ce 4 (pda) 6 ] ring. The rings are further connected by the coordination inter­actions of pda ligands and Ce III , generating a three-dimensional supra­molecular framework.

Poly[diaquatris(μ4-1,3-phenylenediacetato)dicerium(III)]

Poly[diaquatris(μ₄-1,3-phenylenediacetato)dicerium(III)]