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In the title compound, [Bi(C 20 H 23 N)(CF 3 SO 3 )], the Bi III  ion shows a distorted pseudo-trigonal–bipyramidal geometry, with two C atoms and a lone electron pair of the Bi atom in equatorial positions and the N and O atoms at the apical positions. The cyclo­hexyl group is disordered over two orientations with site-occupancy factors of 0.600 (14) and 0.400 (14).

6-Cyclohexyl-6,7-dihydrodibenzo[c,f][1,5]azabismocin-12(5H)-yl(N→Bi) trifluoromethanesulfonate