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The title coordination polymer, [CdBr 2 (C 8 H 8 N 4 ) 2 ]  n  , arose from a layer-separated diffusion synthesis at room temperature. The title compound is isotypic with the I and Cl analogues. The Cd atom, located on an inversion center, is coordinated by two bromide ions and four N atoms (two from triazole rings and two from pyridyl rings) in a distorted  trans -CdBr 2 N 4  octa­hedral arrangement. The bridging 1-(4-pyridyl­meth­yl)-1 H -1,2,4-triazole ligands are twisted [dihedral angle between the triazole and pyridine rings = 72.56 (13)°], affording a two-dimensional 4 4  sheet structure in the crystal.

Poly[dibromidobis[μ-1-(pyridin-4-ylmethyl)-1H-1,2,4-triazole-κ2N:N′]cadmium]

Poly[dibromidobis[μ-1-(pyridin-4-ylmethyl)-1H-1,2,4-triazole-κ²N:N′]cadmium]