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The title compound, Eu 5 Cd 2 Sb 5 O adopts the Ba 5 Cd 2 Sb 5 F-type structure (Pearson symbol  oC 52), which contains nine crystallographically unique sites in the asymmetric unit, all on special positions. One Eu, two Sb, and the Cd atom have site symmetry  m ..; two other Eu, the third Sb and the O atom have site symmetry  m 2 m ; the remaining Eu atom has 2/ m .. symmetry. Eu atoms fill penta­gonal channels built from corner-sharing CdSb 4  tetra­hedra. The isolated O atom,  i.e. , an oxide ion O 2− , is located in a distorted tetra­hedral cavity formed by four Eu cations.

Pentaeuropium dicadmium pentaantimonide oxide, Eu5Cd2Sb5O

Pentaeuropium dicadmium pentaantimonide oxide, Eu₅Cd₂Sb₅O