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The title compound, [Sn 2 (CH 3 O) 2 Cl 6 (C 3 H 7 NO) 2 ], contains two hexa­coordinated Sn IV  atoms symmetrically bridged by two deprotonated methanol ligands, with an inversion center in the middle of the planar Sn 2 O 2  ring. The other sites of the distorted octa­hedral coordination geometry of the Sn IV  atom are occupied by three Cl atoms and one O atom from a dimethyl­formamide mol­ecule. The complex mol­ecules are connected by weak C—H⋯Cl hydrogen bonds into a two-dimensional supra­molecular network parallel to (10    ).

Di-μ-methanolato-κ4O:O-bis[trichlorido(dimethylformamide-κO)tin(IV)]

Di-μ-methanolato-κ⁴O:O-bis[trichlorido(dimethylformamide-κO)tin(IV)]