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The title compound, [Al(H 2 O) 6 ][Cr(OH) 6 Mo 6 O 18 ]·10H 2 O, hexa­aqua­aluminium hexa­hydroxidoocta­deca­oxido­molybdo­chromate(III) deca­hydrate, crystallizes isotypically with its gallium analogue [Ga(H 2 O) 6 ][Cr(OH) 6 Mo 6 O 18 ].10H 2 O. In the structure of the title compound, both the [Al(H 2 O) 6 ] 3+  cation and the Anderson-type [Cr(OH) 6 Mo 6 O 18 ] 3−  anion lie on centres of inversion. The anion is composed of seven edge-sharing octa­hedra, six of which are MoO 6  octa­hedra that are arranged hexa­gonally around the central Cr(OH) 6  octa­hedron. The anions are linked to each other by O—H⋯O hydrogen bonds into infinite chains along [100]. These chains are further connected with the [Al(H 2 O) 6 ] 3+  cations through O—H⋯O hydrogen bonds into sheets parallel to (01    ). O—H⋯O hydrogen bonds involving all the lattice water mol­ecules finally link the sheets into a three-dimensional network.

[Al(H2O)6][Cr(OH)6Mo6O18]·10H2O

[Al(H₂O)₆][Cr(OH)₆Mo₆O₁₈]·10H₂O