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In the title hydrated mol­ecular salt, [Mg(H 2 O) 6 ](C 13 H 9 BrNO 4 S) 2 ·2H 2 O, the Mg 2+  ion (site symmetry) adopts a near regular MgO 6  octa­hedral coordination geometry. In the anion, the dihedral angle between the aromatic rings is 2.5 (2)° and an intra­molecular O—H⋯N hydrogen bond generates an  S (6) ring. In the crystal, the components are linked by O—H⋯O and O—H⋯Br hydrogen bonds.

Hexaaquamagnesium bis{4-[(5-bromo-2-hydroxybenzylidene)amino]benzenesulfonate} dihydrate