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In the title compound, C 17 H 18 NO 2+ ·Cl − ·H 2 O, a precursor to novel asymmetric catalysts, the N-containing six-membered ring of the tetra­hydro­quinolinium unit assumes a half-boat conformation. In the crystal, inter­molecular O—H⋯O, O—H⋯Cl, N—H⋯Cl and C—H⋯O hydrogen bonds and C—H⋯π inter­actions link the mol­ecules into a three-dimensional network.

(3S)-2-Benzyl-3-carboxy-1,2,3,4-tetrahydroisoquinolinium chloride monohydrate