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Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η 5 -C 9 H 7 )Cl(dppe)] (dppe is diphenylphosphanyl ethane) is treated with NaN 3  in refluxing ethanol, yielding the title compound, [Ru(η 5 -C 9 H 7 )(N 3 )(dppe)] or [Ru(C 9 H 7 )(N 3 )(C 26 H 24 P 2 )]. The Ru(II) atom has a typical piano-stool coordination. The Ru—P bond lengths are 2.284 (2) and 2.235 (2) Å. NMR and MS analyses are in agreement with the structure of the title compound.

Azido[1,2-bis(diphenylphosphanyl)ethane-κ2P,P′](η5-indenyl)ruthenium(II)

Azido[1,2-bis(diphenylphosphanyl)ethane-κ²P,P′](η⁵-indenyl)ruthenium(II)