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In the ionic title complex, (C 13 H 11 N 2 ) 2 [Ni(C 4 N 2 S 2 ) 2 ], the Ni II  ion is located on an inversion centre so the asymmetric unit contains one-half [Ni(mnt) 2 ] 2−  dianion (mnt 2−  is maleonitrile­dithiolate) and one 1-(3-cyano­benz­yl)pyridinium cation ([CNBzPy] + ). The Ni II  ion in the [Ni(mnt) 2 ] 2−  anion is coordinated by four S atoms of two mnt 2−  ligands, and exhibits square-planar coordination geometry. In the [CNBzPy] +  cation, the benzene and pyridine rings are twisted with respect to the C/C/N plane incorporating the methyl­ene C atom that links them. The crystal structure is stabilized by Coulombic inter­actions.

Bis[1-(3-cyanobenzyl)pyridinium] bis(1,2-dicyanoethene-1,2-dithiolato)nickelate(II)