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The title compound, [Sn(C 4 H 9 )(C 13 H 21 N)Cl 3 ]·CH 2 Cl 2 , was obtained by recrystallization of [2-(diisopropyl­amino­meth­yl)phen­yl]tin(IV) butyl dichloride from a CH 2 Cl 2 / n -hexane mixture (1:4  v / v ) in the presence of ambient moisture. Partial hydrolysis led to the title compound, the hydro­chloric acid adduct of the dichloride, having a penta­coordinated Sn atom with a trigonal–bipyramidal C 2 SnCl 3  core. The N atom of the 2-[(diisopropyl­ammonio)­meth­yl]phenyl ligand forms a strong intra­molecular N—H⋯Cl hydrogen bond, resulting in a zwitterionic species, [2-( i Pr 2 HN + CH 2 )C 6 H 4 ]SnBuCl 3− ·CH 2 Cl 2 . Disorder was found in the  n -butyl group, which was refined as disordered over three positions, with site occupancies of 0.22 (1), 0.51 (1) and 0.27 (2).

Butyltrichlorido{2-[(diisopropylammonio)methyl]phenyl}tin(IV) dichloromethane monosolvate