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In the title compound, {[Ag(C 6 H 4 NO 2 )(C 6 H 12 N 4 )(H 2 O)]·2H 2 O}  n  , the Ag I  atom shows a distorted triangular pyramidal geometry,, formed by two N atoms from two hexa­methyl­ene­tetra­amine (hmt) ligands and one N atom from a pyridine-4-carboxyl­ate (4-pdc) ligand and one water mol­ecule. The hmt ligands bridge the Ag atoms, forming a chain along [001]. The carboxyl­ate group of the 4-pdc ligand is uncoordinated. O—H⋯O hydrogen bonds between the water mol­ecules and carboxyl­ate groups stabilize the structure.

catena-Poly[[[aqua(pyridine-4-carboxylato-κN)silver(I)]-μ-hexamethylenetetraamine-κ2N:N′] dihydrate]

catena-Poly[[[aqua(pyridine-4-carboxylato-κN)silver(I)]-μ-hexamethylenetetraamine-κ²N:N′] dihydrate]