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In the title compound, [Cu(C 19 H 12 N 5 )(C 2 N 3 )(CH 3 OH)], the Cu II  atom is coordinated by three N atoms from an anionic 2,6-bis­(1 H -benzimidazol-2-yl)pyridine (bbp) ligand, an O atom from a methanol mol­ecule and one N atom from a dicyanamide anion. The crystal structure is stabilized by O—H⋯N and N—H⋯N hydrogen bonds, forming a three-dimensional network.

acta crystallographica. section e

{2-[6-(1H-Benzimidazol-2-yl-κN3)-2-pyridyl-κN]benzimidazolato-κN}(dicyanamido-κN)(methanol-κO)copper(II)